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It was a short story where Tony created an AI (like redwing) for Steve and Sam told Steve he had to teach it. Steve taught it what being a hero was and the AI decided based on that definition that Steve was a villain. Might have been part of a collection of unconnected stories. Been looking for it for days. thx

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magika-draconia.livejournal.com

Sounds like it could be Save The Cheerleader (https://archiveofourown.org/works/15836334/chapters/36877524) by Cartonsofcartoons, although it was Shuri who created the AI, and is, unfortunately, unfinished.

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Looking for fic: Tony makes Steve an AI