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Either Bucky leaves Wakanda by himself or its set before civil war but Bucky gets his hands on a scientist Hydra has either kidnapped or want to, who has developed a chip/program that can break through any computer program.
I remember that a strike team kills the scientist and seriously injures Bucky but he gets away and calls Tony who shows up in the maybe in the armor at the hospital.
I know its not much but it's centered around Tony and Bucky.
Thanks.

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Fractures (Filled With Liquid Gold) - Itsallavengers
https://archiveofourown.org/works/10913913?view_full_work=true

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