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I read a few years ago a story that Tony under a pseudonym had a medical degree and after New York he became the avengers doctor. He I think also talked Bruce into getting a medical degree.

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penumbria.livejournal.com

Only Different in the Details by LadyShadowphyre

Summary: It started slowly, which is why it took so long for anyone to catch on to the changed relationship. At the same time, it started very quickly, which is why no one could quite pin down when it was that Tony Stark and Clint Barton - strangers until that first battle together - had looked at each other and connected.

Written for the prompt at avengerkink Round 13: Clint/Tony, nobody saw it coming.

http://archiveofourown.org/works/567367

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Tony Stark has medical degree