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Date: 2016-03-09 10:35 pm (UTC)http://archiveofourown.org/works/3147836
Fits most of what you're looking for but Darcy and Steve weren't dating, they just ended up sleeping together the one time as a comfort thing before Steve left. Also just so you know the fic ends up as Steve/Darcy/Bucky in case that's not something you're into.